The nation's president Daniel Noboa came out unharmed following his presidential motorcade was attacked by stone-throwing protesters and what officials described as potential shots.
The president was opening a water purification facility in the country's central region when his convoy was set upon by a large group protesting against increasing fuel prices.
About 500 people appeared and were hurling rocks at him, and there are obviously gunshot impacts on the official vehicle
commented Ecuador's environment minister.
Authorities confirmed that five people were detained and would stand court proceedings on terrorism charges – an crime carrying a maximum punishment of three decades in jail.
Video footage made public by the administration depicts demonstrators standing in the street, draped in flags, scrambling to gather sizeable rocks and building blocks.
As the presidential SUV drove by, projectiles slammed into the exterior and broke windows.
Someone could be heard shouting: "Heads down! Get down!" as the vehicle accelerated from the scene.
Officials indicated they were continuing to examine whether certain of the impact marks on the president's protected vehicle were resulted from gunfire.
The alleged attack came amid days of progressively aggressive protests triggered by a government decision to increase diesel prices.
Demonstrators have gone on strike, blocked roads and taken 16 soldiers – who were eventually freed unharmed.
Ecuador's largest Indigenous organization reported that a protester had been killed by security personnel during a the rallies.
Over one hundred individuals, including demonstrators and law enforcement, are thought to have been injured in the violence.
Noboa has imposed a state of emergency across multiple provinces.
Noboa's office stated on digital platforms after the incident that "such actions will not stop" the president.
A senior official of the Organization of American States said that "such violent acts are an assault on democratic principles, stability, and the spirit of harmonious living that must dominate in our nations."
Noboa is trying to reduce fuel support to save about $1bn in government spending, diverting much of the funds to safety initiatives.
Ecuador, once considered one of Latin America's safest countries, has experienced a dramatic surge in criminal activity in the past few years.
Strategically located between two neighboring countries, two of the planet's biggest drug manufacturers, the country has become a significant transit hub for narcotics.
Authorities have accused drug gangs of exacerbating the unrest, implying that illegal organizations are taking advantage of the protests to destabilize the country.
It is estimated that 70% of the world's illegal drug market transits via Ecuador, much of it destined for the US.
This business has attracted international criminal organizations, including Mexican drug cartels, Italy's 'Ndrangheta, and Albania's mafia.
The rivalry for control of trafficking routes has turned Ecuador into one of the region's highest-risk places.
Noboa has called for a public vote to allow the presence of American military to the country, repealing a 2009 ban on international military installations.
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